Geochemistry · Petrology · SIMS

Kenji Shimizu 清水 健二

Senior Researcher in Earth and Planetary Geochemistry

Kochi Institute for Core Sample Research, JAMSTEC

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Background & Profile

Kenji Shimizu

Kenji Shimizu

Senior Researcher
Kochi Institute for Core Sample Research
JAMSTEC

  • PhD, Tokyo Institute of Technology (2002)
  • BSc, Tokyo Institute of Technology (1997)
  • Nankoku, Kochi, Japan
  • shimmy@jamstec.go.jp

I am a senior researcher at the Kochi Institute for Core Sample Research (KOCHI), Japan Agency for Marine-Earth Science and Technology (JAMSTEC). My research centers on the behavior of volatile elements — including water (H₂O), carbon dioxide (CO₂), sulfur, fluorine, and chlorine — in Earth's interior, with the goal of understanding their origin and deep-Earth cycling.

My primary analytical tool is Secondary Ion Mass Spectrometry (SIMS), a microbeam technique that enables in situ isotope ratio and trace-element measurements at the scale of individual minerals, volcanic glasses, and melt inclusions. These tiny "time capsules" trapped within crystals preserve geochemical records of magmas before they degas, making them indispensable archives of the deep volatile budget.

My work spans a wide range of geological systems: subduction zones and arc volcanoes (constraining volatile fluxes and slab-derived contributions), mid-ocean ridges and oceanic plateaus (reconstructing mantle heterogeneity and plume dynamics), and ancient komatiites (tracing early Earth geodynamics). More recently, I have extended my interest to the hydrogen isotope (δD) systematics of magmatic systems, using SIMS-based water and hydrogen measurements to trace the fate of subducted lithosphere into the mantle transition zone.

I am also involved in developing analytical protocols and reference materials for volatile measurement by SIMS, including fluorine, chlorine, sulfur, and water in silicate glasses — work that supports the broader geochemical community.

SIMS Volatile Elements Melt Inclusions Hydrogen Isotopes Mantle Geochemistry Subduction Zones Oceanic Plateaus Arc Volcanism Komatiites Deep-Earth Water Cycle
Massive MORB glass and melt inclusion in olivine

Research Themes

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Volatiles in the Deep Earth

Quantifying H₂O, CO₂, F, S, and Cl by SIMS across a range of geomaterials — volcanic glasses, melt inclusions, mantle minerals (olivine, pyroxene, bridgmanite), and hydrous minerals such as apatite — to constrain the budget and cycling of volatile elements through Earth's mantle, crust, and surface reservoirs.

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SIMS Microanalysis & Method Development

Developing and refining SIMS protocols for in situ isotope ratio measurements (H, S) and trace volatile analyses in silicate glasses, including calibration standards and matrix-effect corrections.

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Arc Magmatism & Subduction Zones

Using melt inclusions from arc volcanoes (Japan, Izu-Bonin-Mariana) to trace the transfer of slab-derived volatiles into the mantle wedge and the role of these fluids in arc magma genesis.

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Oceanic Large Igneous Provinces

Investigating the geochemistry and volatile contents of the Ontong Java Plateau and Shatsky Rise to understand the origin of mantle plumes and their role in Earth's geological history.

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Polishing Method Development PATENT

SIMS analysis demands a perfectly flat, mirror-polished surface — yet conventional polishing of rocks (composite materials of minerals with different hardness) is slow, skill-dependent, and prone to "relief" artifacts where soft phases are undercut. I developed a grooved polishing plate with a hexagonal hole pattern that enables anyone to produce a smooth, flat surface quickly and easily using standard lapping films. The method is applicable not only to geological samples but to any composite material, including battery cross-sections and coated surfaces in materials science and industry.

Published: Journal of Society of Automotive Engineers of Japan, Vol.78, No.1 (2024)

Komatiite outcrop, Gorgona Island Grooved polishing plates with hexagonal hole pattern

Selected Publications

2025

Magmatic evolution and timescales of the Naruko caldera system (NE Honshu): Insight from orthopyroxene and quartz mineral zoning

Kotov A., Tsuchiya N., Okumura S., Ban M., Uno M., Miyagi I., Shimizu K., Ushikubo T., et al.

Journal of Volcanology and Geothermal Research, 467, 108415

2024

Oceanic and Sedimentary Microbial Sulfur Cycling Controlled by Local Organic Matter Flux During the Ediacaran Shuram Excursion in the Three Gorges Area, South China

Matsu'ura F., Sawaki Y., Komiya T., Han J., Maruyama S., Ushikubo T., Shimizu K., Ueno Y.

Geobiology, 22(5)

2024

ND70 Series Basaltic Glass Reference Materials for Volatile Element Measurement and the C Ionisation Efficiency Suppression Effect of Water in Silicate Glasses in SIMS

Moussallam Y., Towbin W.H., Plank T., Bureau H., Khodja H., Guan Y., Ma C., Baker M.B., Stolper E.M., Naab F.U., Shimizu K., et al.

Geostandards and Geoanalytical Research, 48(3), 637–660

2023

Hydrogen incorporation mechanism in the lower-mantle bridgmanite

Purevjav N., Tomioka N., Yamashita S., Shinoda K., Kobayashi S., Shimizu K., Ito M., Fu S., Gu J., Hoffmann C., et al.

American Mineralogist

2023

New evidence for the Ontong Java Nui hypothesis

Tejada M.L.G., Sano T., Hanyu T., Koppers A.A.P., Nakanishi M., Miyazaki T., Ishikawa A., Tani K., Shimizu S., Shimizu K., et al.

Scientific Reports, 13(1)

2022

Sulfur isotope and trace element systematics in arc magmas: seeing through the degassing via a melt inclusion study of Kyushu Island volcanoes, Japan

Kawaguchi M., Koga K.T., Rose-Koga E., Shimizu K., Ushikubo T., Yoshiasa A.

Journal of Petrology, 63(7)

2022

Water enrichment in the mid-ocean ridge by recycling of mantle wedge residue

Liu J., Tao C., Zhou J., Shimizu K., Li W., Liang J., Liao S., Kuritani T., Deloule E., Ushikubo T., et al.

Earth and Planetary Science Letters, 584, 117455

2022

Modification for the matrix effect in SIMS-derived water contents of silicate glasses

Shimizu K., Ushikubo T., Kuritani T., Hirano N., Yamashita S.

Geochemical Journal

2021

Tracing the subducting Pacific slab to the mantle transition zone with hydrogen isotopes

Kuritani T., Shimizu K., Ushikubo T., Xia Q.-K., Liu J., Nakagawa M., Taniuchi H., Sato E., Doi N.

Scientific Reports, 11(1)

2021

Microbial sulfate reduction plays an important role at the initial stage of subseafloor sulfide mineralization

Nozaki T., Nagase T., Ushikubo T., Shimizu K., Ishibashi J.

Geology, 49(2), 222–227

2021

Covariation of Slab Tracers, Volatiles, and Oxidation During Subduction Initiation

Brounce M., Reagan M.K., Kelley K.A., Cottrell E., Shimizu K., Almeev R.

Geochemistry, Geophysics, Geosystems, 22(6)

2021

Survey of impact glasses in shergottites searching for Martian sulfate using X-ray absorption near-edge structure

Shidare M., Nakada R., Usui T., Tobita M., Shimizu K., Takahashi Y., Yokoyama T.

Geochimica et Cosmochimica Acta, 313, 85–98

2021

Persistent gas emission originating from a deep basaltic magma reservoir of an active volcano: the case of Aso volcano, Japan

Kawaguchi M., Hasenaka T., Koga K.T., Rose-Koga E.F., Yasuda A., Hokanishi N., Mori Y., Shimizu K., Ushikubo T.

Contributions to Mineralogy and Petrology, 176(1)

2020

Temporal Evolution of Proto-Izu-Bonin-Mariana Arc Volcanism over 10 Myr: Constraints from Statistical Analysis of Melt Inclusion Compositions

Hamada M., Iwamori H., Brandl P.A., Ushikubo T., Shimizu K., Ito M., Li H., Savov I.P.

Journal of Petrology, 61(1)

2020

Determination of total CO₂ in melt inclusions with shrinkage bubbles

Hanyu T., Yamamoto J., Kimoto K., Shimizu K., Ushikubo T.

Chemical Geology, 557

2019

Tiny droplets of ocean island basalts unveil Earth's deep chlorine cycle

Hanyu T., Shimizu K., Ushikubo T., Kimura J.-I., et al.

Nature Communications, 10(1)

2019

In situ analyses of hydrogen and sulfur isotope ratios in basaltic glass using SIMS

Shimizu K., Ushikubo T., Murai T., Matsu'ura F., Ueno Y.

Geochemical Journal, 53(3), 195–207

2019

Identifying volatile mantle trend with the water–fluorine–cerium systematics of basaltic glass

Shimizu K., Ito M., Chang Q., Miyazaki T., et al.

Chemical Geology, 522, 283–294

2017

H₂O, CO₂, F, S, Cl, and P₂O₅ analyses of silicate glasses using SIMS: Report of volatile standard glasses

Shimizu K., Ushikubo T., Hamada M., Itoh S., Higashi Y., Takahashi E., Ito M.

Geochemical Journal, 51(4), 299–313

2015

Simultaneous determinations of fluorine, chlorine, and sulfur in rock samples by ion chromatography combined with pyrohydrolysis

Shimizu K., Suzuki K., Saitoh M., Konno U., Kawagucci S., Ueno Y.

Geochemical Journal, 49(1), 113–124

2013

Paleo-elevation and subsidence of ~145 Ma Shatsky Rise inferred from CO₂ and H₂O in fresh volcanic glass

Shimizu K., Shimizu N., Sano T., et al.

Earth and Planetary Science Letters, 383

2011

Flux-Free Fusion of Silicate Rock Preceding Acid Digestion for ICP-MS Bulk Analysis

Shimizu K., Chang Q., Nakamura K.

Geostandards and Geoanalytical Research, 35(1), 45–55

2009

CO₂-rich komatiitic melt inclusions in Cr-spinels within beach sand from Gorgona Island, Colombia

Shimizu K., Shimizu N., Komiya T., et al.

Earth and Planetary Science Letters, 288(1–2)

2005

The geochemistry of ultramafic to mafic volcanics from the Belingwe greenstone belt, Zimbabwe

Shimizu K., Nakamura E., Maruyama S.

Journal of Petrology, 46(11)

2004

Discovery of Archean continental and mantle fragments inferred from xenocrysts in komatiites, the Belingwe greenstone belt, Zimbabwe

Shimizu K., Nakamura E., Kobayashi K., Maruyama S.

Geology, 32(4)

2001

Cr-spinel, an excellent micro-container for retaining primitive melts

Shimizu K., Komiya T., Hirose K., Shimizu N., Maruyama S.

Earth and Planetary Science Letters, 189(3–4)

★ = First or corresponding author  |  Full list available on ResearchMap (60+ papers)

Full Publication List on ResearchMap

Get in Touch

I welcome inquiries from students, collaborators, and colleagues interested in geochemistry, volatile studies, or SIMS analytics. Please feel free to reach out.

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Institution

Kochi Institute for Core Sample Research (KOCHI)
JAMSTEC
200 Monobe-otsu, Nankoku, Kochi 783-8502, Japan
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External Profiles